ELF AUTOCHEM NORTH AMERICA FLUOROCHEMICALS -- FORANE 134A -- 6830-01-370-6207
===================== Product Identification ===================== Product ID:FORANE 134A MSDS Date:01/29/1998 FSC:6830 NIIN:01-370-6207 Status Code:A === Responsible Party === Company Name:ELF AUTOCHEM NORTH AMERICA FLUOROCHEMICALS Address:2000 MARKET ST City:PHILADELPHIA State:PA ZIP:19103-3222 Country:US Info Phone Num:215-419-7704\7695 Emergency Phone Num:215-419-7695\7704 Chemtrec Ind/Phone:(800)424-9300 CAGE:TO328 === Contractor Identification === Company Name:ELF ATOCHEM NORTH AMERICA INC Address:2000 MARKET STREET Box:City:PHILADELPHIA State:PA ZIP:19103-3222 Country:US Phone:800-245-5858 CAGE:86460 Company Name:ELF AUTOCHEM NORTH AMERICA FLUOROCHEMICALS Address:2000 MARKET ST Box:City:PHILADELPHIA State:PA ZIP:19103-3222 Country:US Phone:215-419-7704\7695 CAGE:TO328 Company Name:REFRIGERANT RECLAIM SERVICES INC / DBA FULL CYCLE Address:121 S NORWOOD DR Box:City:HURST State:TX ZIP:76053 Country:US Phone:817-282-0022 Contract Num:SP0450-99-C5460 CAGE:0YD89 ============= Composition/Information on Ingredients ============= Ingred Name:1,1,1,2-TETRAFLUOROETHANE (R134A) CAS:811-97-2 Fraction by Wt: 100% ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:TARGET ORGANS: CNS, RESPIRATORY SYSTEM AND HEART. EYES: VERY SLIGHT IRRITATION. RAPID VOLATILIZATION OF LIQUID MAY CAUSE FROSTBITE. SKIN: SLIGHT IRRITANT, CONTACT MAY CAUSE FROSTBITE. INHALATION: CONC ENTRATED VAPORS CAN PRODUCE RAPID ANESTHETIC EFFECTS, RESPIRATORY DEPRESSION, INCREASED SENSITIVITY OF THE HEART TO ADRENALINE, DEPRESSION OF CARDIAC FUNCTION, DEATH DUE TO ASPHYXIATION. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION, FROSTBITES AND PAIN, DROWSINESS, UNCONSCIOUSNESS, RAPID HEARTBEAT, IRREGULAR HEARTBEAT. Medical Cond Aggravated by Exposure:PREEXISTING HEART DISEASE OR COMPROMISED HEART FUNCTION SHOULD ONLY HAVE LIMITED EXPOSURE TO THIS MATERIAL. ======================= First Aid Measures ======================= First Aid:SKIN: IF FROSTBITTEN, WARM SLOWLY W/WATER. FLUSH W/PLENTY OF WATER. EYES: FLUSH W/PLENTY OF CLEAN WATER FOR 15 MINS. INHALATION: REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE CPR. IF BREATHING IS DIFFIC ULT, GIVE OXYGEN. INGESTION: NEVER GIVEANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point:NONFLAMMABLE Autoignition Temp:Autoignition Temp Text:N/E Extinguishing Media:USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING FIRE CONDITIONS. Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS IF FIGHTING FIRES NEAR THIS PRODUCT DUE TO TOXICITY OF THERMAL DECOMPOSITION PRODUCTS.KEEP CONTAINERS COOL. Unusual Fire/Explosion Hazard:MIXTURES OF HFC-134A WITH AIR OR OTHER OXIDIZERS UNDER HIGH TEMPERATURE AND PRESSURE, CAN BE FLAMMABLE.IN TESTS CONDUCTED AT UP TO 170C, HFC-134A IS FLAMMABLE ONLY AT PRESSURES ABOVE 50PSIA AND WITH M ORE THAN 50% AIR BY VOLUME.MIXTURES CONTAINING HFC-134A SHOULD NOT BE USED FOR PRESSURE OR LEAK TESTING. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE/EXTINGUISH IGNITION/COMBUSTION SOURCES. EVACUATE ENCLOSED SPACES UNTIL GAS IS DISPERSED. KEEP UPWIND. STOP LEAK IF POSSIBLE W/OUT RISK. DISPERSE GAS W/FLOOR-LEVEL FORCED-AIR VENTILATION. EXHAUS T VAPORS OUTDOORS. REMOVE FLAMES/HEAT ====================== Handling and Storage ====================== Handling and Storage Precautions:KEEP AWAY FROM IGNITION SOURCES AND DIRECT SUNLIGHT. STORE BELOW 120F. STORE IN TIGHTLY CLOSED CONTAINES. DO NOT REFILL THIS CYLINDER. EMPTY CONTAINERS CONTAIN HAZARDOUS RESIDUE. Other Precautions:DON'T DROP, REUSE/REFILL CONTAINER. DON'T CUT, GRIND/ WELD ON/NEAR CONTAINER. DON'T GET IN EYES, ON SKIN/CLOTHING. DON'T BREATHE VAPOR, MIST/GAS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IN INADEQUATELY VENTILATED AREAS, A NIOSH/MSHA APPROVED (TC-18C) SUPPLIED AIR RESPIRATOR/SCBA IS REQUIRED. Ventilation:CHECK AIR FOR CONTAMINANT & FOR OXYGEN DEFICIENCY. USE LOCAL EXHAUST SYSTEM IF VENTILATION IS INADEQUATE. Protective Gloves:SYNTHETIC RUBBER/NEOPRENE Eye Protection:CHEMICAL GOGGLES Other Protective Equipment:WEAR APPROPRIATE CHEMICAL RESISTANT PROTECTIVE CLOTHING TO PREVENT SKIN CONTACT. Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. DESTROY CONTAMINATED SHOES. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:G3 Boiling Pt:=-26.3C, -15.5F Melt/Freeze Pt:=-101.C, -149.8F Vapor Pres:96.16 PSIA @77F Vapor Density:3.52 Spec Gravity:1.21 @ 77F Solubility in Water:NEGLIGIBLE Appearance and Odor:CLEAR, COLORLESS LIQUIFIED GAS WITH FAINT ETHEREAL(ETHER-LIKE) ODOR Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES AVOID CONTACT WITH STRONG ALKALI OR ALKALINE EARTH METALS, ALUMINUM, MAGNESIUM/ZINC & STRONG OXIDIZERS SINCE THEY MAY REACT WITH OR ACCELERATE DECOMPOSITION OF THIS MATERIAL. Stability Condition to Avoid:THERMAL DECOMPOSITION DUE TO EXPOSURE TO HEAT(>800F) OR FIRE FLAMES,EXTREMELY HOT METAL SURFACES,HEATING ELEMENTS,COMBUSTION ENGINES,ETC Hazardous Decomposition Products:HYDROGEN FLUORIDE, CO, CO2 =================== Toxicological Information =================== Toxicological Information:INHALATION: 4 HR LC50 RATS= 500,000 PPM; 30 MIN LC50= 750,000 PPM. CONCENTRATION >50,000 PPM PRODUCED ANESTHETIC EFFECT IS MICE, DOG, CATS AND MOKEYS. NO TOXIC EFFECTS WERE OBSERVED IN RATS EXPOSED 6 HR/DAY, 5 DAYS/WEEK FOR 13 WEEKS FOR CONCENTRATIONS UPTO 50,000 PPM. INHALATION FOLLOWED BY IV INJECTION OF EPINEPHRINE RESULTED IN HEART SENSITIZATIONS AT LEVELS >75,000 PPM IN DOGS. ===================== Ecological Information ===================== Ecological:A 28 DAY BIODEGRADATION STUDY WITH HFC 134A USING AN ACTIVATED SLUDGE INOCULUM PRODUCED 3% BIODEGRADATION. ==================== Disposal Considerations ==================== Waste Disposal Methods:RECYCLE/RECLAIM IF POSSIBLE. RECLAIMED MATERIAL MAY BE INCINERATED BUT TOXIC & CORROSIVE COMBUSTION PRODUCTS(HF & HCL) MUST BE HANDLED APPROPRIATELY. DISPOSE OF IAW/LOCAL, STATE & FEDERAL REGULATIONS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.