TELEDYNE SYSTEMS CO -- LITHIUM METAL -- 6135-01-274-0740
===================== Product Identification ===================== Product ID:LITHIUM METAL MSDS Date:05/22/1989 FSC:6135 NIIN:01-274-0740 === Responsible Party === Company Name:TELEDYNE SYSTEMS CO Address:19601 NORDHOFF ST City:NORTHRIDGE State:CA ZIP:91324-2422 Country:US Info Phone Num:818-886-2211 Emergency Phone Num:818-886-2211 Preparer's Name:D B COGHLAN CAGE:17863 === Contractor Identification === Company Name:CHEMETALL FOOTE CORPORATION Address:348 HOLIDAY INN DR Box:City:KINGS MOUNTAIN State:NC ZIP:28086 Country:US Phone:704-739-2501 CAGE:07660 Company Name:LITTON SYSTEMS INC,GUIDANCE AND CONTROL SYSTEMS DIV Address:19601 NORDHOFF ST Box:City:NORTHRIDGE State:CA ZIP:91324-2422 Country:US Phone:818-886-2211 CAGE:17863 ============= Composition/Information on Ingredients ============= Ingred Name:LITHIUM CAS:7439-93-2 RTECS #:OJ5540000 Fraction by Wt: 99.8% ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NO Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:LITHIUM REACTS W/BODY MOISTURE TO FORM LITHIUM HYDROXIDE CAUSING A BURNING SENSATION. THERE IS NO KNOWN LONG-TERM HAZARD FROM LITHIUM IN ITS SOLID STATE, WHEN NOT FOUND IN RESPIRABLE DUST. THE PRIMARY HEALTH HAZARD IS FROM BURNING LITHIUM. Explanation of Carcinogenicity:NONE Effects of Overexposure:LITHIUM REACTS W/BODY MOISTURE TO FORM LITHIUM HYDROXIDE CAUSING A BURNING SENSATION. THERE IS NO KNOWN LONG-TERM HAZARD FROM LITHIUM IN ITS SOLID STATE, WHEN NOT FOUND IN RESPIRABLE DUST. THE PRIMARY HEALTH HAZARD IS FROM BURNING LITHIUM. ======================= First Aid Measures ======================= First Aid:SOLID: SKIN: REMOVE SOLID METAL & WASH THOROUGHLY W/WATER TO AVOID CAUSTIC BURN. FOLLOW W/NEUTRALIZING SOLUTION. EYES: FLUSH W/POTABLE WATER FOR 15 MINS W/BURNED EYE NEAREST THE FLOOR SO CHEMICAL ISN' T WASHED INTO OTHER EYE. MOLTEN: REMOVEAS RAPIDLY AS POSSIBLE. FLOOD AREA W/MINERAL OIL & SCRAPE LITHIUM AWAY. FOLLOW W/NEUTRALIZING SOLUTION. TREAT FOR SHOCK. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Extinguishing Media:LITH-X IS RECOMMENDED FOR LITHIUM FIRES. DON'T USE WATER/CO2. Fire Fighting Procedures:NEVER FIGHT LITHIUM FIRE ALONE. SCBA & FIRE FIGHTING ENTRY SUITS REQUIRED WHEN FIGHTING FIRES IN CONFINED SPACES. IF LARGE PROPORTIONS ARE REACHED, LET IT BURN. Unusual Fire/Explosion Hazard:MOLTEN PRODUCT REACTS EXPLOSIVELY W/WATER/CONCRETE FLOORING. REIGNITION CAN OCCUR IF THE LITH-X BLANKET IS DISTURBED. FLAMMABLE SOLID. DANGEROUS WHEN WET. ================== Accidental Release Measures ================== Spill Release Procedures:RETURN TO A SEALED CONTAINER & COAT W/WHITE MINERAL OIL. IF LITHIUM BEGINS TO REACT W/MOISTURE IN THE AIR, REMOVE TO AN ISOLATED AREA & ALLOW IT TO BURN. IF LITHIUM CAN'T BE REMOVED, FOLLOW FIRE FIGHT ING PROCEDURES. DON'T ALLOW WATER CONTAMINATION. ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN ISOLATED AREA FREE FROM SOURCES OF WATER, INCLUDING SPRINKLER SYSTEMS, & OTHER COMBUSTIBLE MATERIALS. BUCKETS OF LITH-X SHOULD BE AVAILABLE. Other Precautions:IF VAPORS FROM MOLTEN LITHIUM CONDENSE ON EQUIPMENT, CLEAN BEFORE EXPOSING TO AIR TO AVOID A FLASH FIRE. WEAR APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT TO AVOID CONTACT W/SKIN/EYES. LITHIUM SHOULD BE USED AS SOON AS POSSIBLE AFTER RECEIPT. ============= Exposure Controls/Personal Protection ============= Ventilation:SHOULD ONLY BE EXPOSED IN DRY INERT GASEOUS ATMOSPHERES/DEHUMIDIFIED AIR. Protective Gloves:SOLID: RUBBER/SURGICAL. MOLTEN: REQUIRED Eye Protection:SOLID: REQUIRED. MOLTEN: FACE SHIELD. Other Protective Equipment:MOLTEN: HARD HAT, FIRE-RETARDANT CLOTHING, ALUMINIZED OVERCOAT, SAFETY SHOES. Work Hygienic Practices:AVOID SKIN CONTACT & INHALATION. Supplemental Safety and Health WASTE DISPOSAL CONT'D: COLLECT THE SOLUTION. DISPOSE OF IN ACCORDANCE W/FEDERAL, STATE & LOCAL REGULATIONS. UN1415. ================== Physical/Chemical Properties ================== Melt/Freeze Pt:M.P/F.P Text:356.9F Vapor Pres:0 Vapor Density:0.534 Appearance and Odor:SOFT METALLIC SILVER COLORED SOLID W/NO ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES WATER, CONCRETE FLOORING, AIR, OXYGEN, NITROGEN, CO2, ACID, HALOGENS & MANY CHEMICALS Stability Condition to Avoid:ELEVATED TEMPERATURES, OPEN FLAME & SPARK-GENERATING EQUIPMENT, MOLTEN & SOLID LITHIUM IN WATER Hazardous Decomposition Products:WHITE, CAUSTIC LITHIUM OXIDE SMOKE, HYDROGEN ==================== Disposal Considerations ==================== Waste Disposal Methods:MATERIAL NOT DETERIORATED/CONTAMINATED MAY, W/PRIOR APPROVAL, BE RETURNED TO FOOTE IN DOT APPROVED CONTAINERS FOR REPROCESSING. HEAVILY NITRIDED METAL MAY BE DISPOSED OF BY SLOW AMBIENT AIR OXIDATION IN AN OPEN AREA PROTECTED FROM RAIN. (SEE SUPP) Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.