MALLINKRODT BAKER, INC. -- PETROLEUM ETHER -- 6810-00-227-1307
===================== Product Identification ===================== Product ID:PETROLEUM ETHER MSDS Date:12/08/1996 FSC:6810 NIIN:00-227-1307 === Responsible Party === Company Name:MALLINKRODT BAKER, INC. Address:222 RED SCHOOL LANE Box:M City:PHILLIPSBURG State:NJ ZIP:08865 Country:US Info Phone Num:800-582-2537 Emergency Phone Num:800-424-9300 CHEMTREC Preparer's Name:STRATEGIC SERVICES DIV Chemtrec Ind/Phone:(800)424-9300 CAGE:IO255 === Contractor Identification === Company Name:MALLINCKRODT SPECIALTY CHEMICALS CO Address:222 RED SCHOOL LANE Box:City:PHILLIPSBURG State:NJ ZIP:08865 Country:US Phone:908-859-2151 CAGE:62910 Company Name:MALLINKRODT BAKER INC Address:222 RED SCHOOL LANE Box:M City:PHILLIPSBURG State:NJ ZIP:08865 Country:US Phone:800-582-2537 CAGE:IO255 Company Name:PHOENIX INDUSTRIES INC Address:1519 CHAMBERLAYNE PARKWAY Box:City:RICHMOND State:VA ZIP:23222 Country:US Phone:804-264-5183/FAX: 264-5535 CAGE:0YED2 ============= Composition/Information on Ingredients ============= Ingred Name:VM&P NAPHTHA (LIGROINE) CAS:8032-32-4 RTECS #:OI6180000 Fraction by Wt: 90-100% Other REC Limits:NONE RECOMMENDED OSHA PEL:300 PPM ACGIH TLV:300 PPM; 9596 ===================== Hazards Identification ===================== LD50 LC50 Mixture:INHALATION (RAT) LC50: 3400 PPM/4HR Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:INHALATION MAY CAUSE SYMPTOMS OF INTOXIFICATION & PERIPHERAL NERVE DISORDERS & CNS DEPRESSION; MAY CAUSE THROAT IRRITATION. MAY CAUSE SKIN & EYE IRRITATION. INGESTION MAY CAUSE NERVOUS SYSTEM DISORDER S, GI TRACT IRRITATION. ASPIRATION MAY CAUSE CHEMICAL PNEUMONITIS. PROLONGED OVEREXPOSURE MAY CAUSE SKIN DERMATITIS. Explanation of Carcinogenicity:NO INGREDIENT OF A CONCENTRATION OF 0.1% OR GREATER IS LISTED AS A CARCINGEN BY NTP, IARC NOR IS REGULATED BY OSHA. Effects of Overexposure:INHALED-LOSS OF APPETITE, MUSCLE WEAKNESS, IMPAIRMENT OF MOTOR ACTION, DIZZINESS, DROWSINESS, THROAT IRRITATION. INGESTED-LOCAL BURNING SENSATION IN MOUTH, ESOPHAGUS, STAMOACH; VOMITING, BLURRED VISIO N, DIARRHEA. SKIN-IRRITATION. EYES-REDNESS, PAIN. Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN DISORDERS OR EYE PROBLEMS, OR IMPAIRED LIVER, KIDNEY OR RESPIRATORY FUNCTION MAY BE MORE SUSCEPTIBLE TO THE EFFECTS OF THE SUBSTANCE. ======================= First Aid Measures ======================= First Aid:INHALATION-REMOVE TO FRESH AIR. GIVE ARTIFICIAL RESPIRATION IF NOT BREATHING; OXYGEN IF BREATHING DIFFICULT. CALL A PHYSICIAN. INGESTED-DO NOT INDUCE VOMITING! IF VOMITING OCCURS, KEEP HEAD BELOW HIPS . NEVER GIVE ANYTHING BY MOUTH IF UNCONSCIOUS. CALL A PHYSICIAN IMMEDIATELY. SKIN-REMOVE CONTAMINATED CLOTHES. IMMEDIATELY FLUSH WITH WATER. EYES-IMMEDIATELY FLUSH WITH WATER, LIFT LIDS. CALL DOCTOR. ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:=-17.6C, 0.F Autoignition Temp:=287.8C, 550.F Lower Limits:1 Upper Limits:6 Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, FOAM. WATER MAY BE INEFFECTIVE. DO NOT ALLOW WATER RUNOFF TO ENTER SEWERS OR WATERWAYS. Fire Fighting Procedures:IN THE EVENT OF A FIRE, WEAR FULL PROTECTIVE CLOTHING & NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS. WATER MAY BE USED TO COOL FIRE EXPOSED CONTAINERS. Unusual Fire/Explosion Hazard:EXTREMELY FLAMMABLE LIQUID & VAPOR!VAPOR MAY CAUSE FLASH FIRE.DANGEROUS FIRE HAZARD WHEN EXPOSED TO HEAT OR FLAME.CONTACT WITH STRONG OXIDIZERS MAY CAUSE FIRE. ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE AREA. REMOVE ALL SOURCES OF IGNIITON. WEAR APPROPRIATE PERSONAL PROTECTIVE GEAR. ISOALTE AREA & DENY ENTRY. CONTAIN & RECOVER LIQUID. USE NON-SPARKING TOOLS. ABSORB W/INERT MATERIAL & PLACE IN CONTAINER FOR DISPOSAL. DO NOT FLUSHTO SEWER! Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL, DRY, WELL-VENTILATED PLACE AWAY FROM SOURCES OF IGNITION. PROTECT FROM PHYSICAL DAMAGE. STORAGE & USE AREAS SHOULD BE NONE SMOKING. Other Precautions:CONTAINERS SHOULD BE GROUNDED & BONDED FOR TRANSFERS TO AVOID STATIC SPARKS. USE NON-SPARKING TOOLS INCLUDING EXPLOSION-PROOF VENTILATION. ISOLATE FROM INCOMATIBLE MATERIALS. EMPTY CONTAINERS MAY BE H AZARDOUS SINCE THEY RETAIN RESIDUE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:A FULL-FACE PIECE ORGANIC VAPOR RESPIRATOR MAY BE WORN UP TO 50 TIMES THE EXPOSUE LIMIT. FOR EMERGENCIES OR WHERE EXPOSURE LEVELS ARE UNKOWN, USE A FULL-FACE SELF-CONTAINED BREATHING APPARATUS. USE IA W 29 CFR 1910.134. Ventilation:LOCAL OR GENERAL EXHAUST (EXPLOSION-PROOF) IS RECOMMENDED TO KEEP EXPOSURES BELOW AIRBORNE EXPOSURE LIMITS. Protective Gloves:IMPERVIOUS-BUTYL, PVA, VITON. Eye Protection:SAFETY GOGGLES/FACESHILD. Other Protective Equipment:BOOTS, LAB COAT, APRON OR COVERALLS AS, APPROPRIATE TO PREVENT SKIN CONTACT. EYE WASH, QUICK-DRENCH SHOWER. Work Hygienic Practices:WASH THOROUGHLY AFTER AHNDLING. AVOID BREATHING VAPOR. AVOID CONTACT WITH EYES, SKIN AND CLOTHING. Supplemental Safety and Health DO NOT OPEN UNLESS CONTENTS ARE AT ROOM TEMPERATURE (72F) OR BELOW FOR AT LEAST 24 HOURS. ================== Physical/Chemical Properties ================== HCC:F1 NRC/State Lic Num:NOT RELEVANT Boiling Pt:=20.C, 68.F Melt/Freeze Pt:=-72.6C, -99.F Vapor Pres:40 Vapor Density:2.5 Spec Gravity:0.6 Evaporation Rate & Reference:10 (N-BUTYL ACETATE=1) Solubility in Water:INSOLUBLE Appearance and Odor:CLEAR, COLORLESS LIQUID; GASOLINE OR KEROSENE ODOR. Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS; WILL ATTACK SOME FORMS OF PLASTICS, RUBBER AND COATINGS. Stability Condition to Avoid:HEAT, FLAME, IGNITION SOURCES, SUNLIGHT AND INCOMPATIBLES. Hazardous Decomposition Products:CARBON MONOXIDE AND CARBON DIOXIDE MAY FORM WHEN HEATED TO DECOMPOSITION. Conditions to Avoid Polymerization:WILL NOT OCCUR. ==================== Disposal Considerations ==================== Waste Disposal Methods:WHATEVER CANNOT BE SAVED FOR RECOVERY OR RECYCLING SHOULD BE HANDLED AS HAZARDOUS WASTE & SENT TO A RCRA APPROVED INCINERATOR OR DISPOSED IN A RCRA APPROVED WASTE FACILITY. PROCESSING, USE OR CONTAMIN ATION MAY CHANGE THE WASTE MANAGEMENT OPTIONS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.